Organic Syntheses, Volume 82

Preparation of Optically Active (R,R)-Hydrobenzoin From Benxoin or Benzil.

2,2-Diethoxy-1-Isoxyanoethane.

Preparation of (S,S) -1,2--BIS(tert-Butylmethylphosphino)-Ethane ((S,S)-t-Bu-BISP) As a Rhodium Complex.

Preparation of Hexakis(4-Bromophenyl)Benzene (HBB).

An Efficient, Highly Diastereo- And Enantioselective Hetero-Diels-Alder Catalyst. Preparation of (2S, 6R)-6-(tert-Butyldimethylsilyloxymethyl)-2-Methoxy-2,5-Diyhdropyran.

Lipase-Catalyzed Resolution of 4-Trimethylsilyl-3-Butyn-2-OL and Conversion of the (R)-Enantiomer To (R)-3-Butyn-2-Yl Mesylate and ({)-1-tributylstannyl-1,2-Butadiene.

Iridium-Catalyzed Synthesis of Vinyl Ethers from Alcohols and Vinyl Acetate.

1-(tert-Butyliminomethyl)-1,3-Dimethylurea Hydrochloride.

Ortho-Formylation of Phenols: Preparation of 3-Bromosalicylaldehyde.

Preparation of 1-Methoxy-2-(4-Methoxyphenoxy)Benzene.

D-Ribonolactone and 2,3-Isopropylidene-(D-Ribonolactone)

Preparation of 4-Acetylamino-2,2,6,6-Tetramethyl-Piperidine-1-Oxoammonium Tetrafluoroborate, and the Oxidation of Geraniol to Geranial.

(2S)-(-)-3exo-(Morpholino)Isoborneol [(-)-MIB].

Conversion of Arylalkylketones Into Dichloroalkenes: 1-Chloro-4-(2,2-Dichloro-1-Methylvinyl)Benzene.

1,4,-Dioxene.

(R)-(+)-3,4-Dimethylcyclohex-2-EN-1-One.

A Practical and Safe Preparation of 3,5-BIS-(Trifluoromethyl)Acetophenone.

Asymmetric Alcoholysis of Meso-Anhydrides Mediated By Alkaloids.

Iridium-Catalyzed C-HBorylation of Arenes and Heteroarenes: 1-Chloro-3-Iodo-5-(4,4,5,5-Tetramethyl-1,3,2,-Dioxaborolan-2-YL)Benzene and 2-(4,4,5,5-Tetramethyl-1,3,2-Dioxaborolan-2-YL)Indole.

Asymmetric Rearrangement of Allylic Trichloroacetimidates: Preparation of (s)-2,2,2-Trichloro-N-(1-Propylallyl)Acetamide.

Preparation of (Triphenylphosphoranylidene)-Ketene From (Methoxycarbonylmethylene)-Triphenylphosphorane.

Preparation of [1-(Methoxymethylcarbamoyl)-Aethyl]Phosphonic Acid BIS(2,2,2-Trifluoroethyl)Ester: A Useful Intermediate in the Synthesis of Z-Unsaturated N-Methoxy-N-Methylamides.

(R_s)-(+)-2-Methyl-2-Propanesulfinamide.

Preparation of 1-Butyl-3-Methylimidazolium Tetrafluoroborate.

Catalytic Asymmetric Acyl Halide-Aldehyde Cyclocondensation reaction.

Alkyne via Solid-Liquid Phase-Transfer Catalyzed Dehydrohalogenation: Acetylene Dicarboxaldehyde Tetramethyl Acetal and Acetylene Dicarboxaldeyde Dimethyl Acetal.

Catalytic reduction of Amides to Amines with Hydrosilanes Using a Tributhenium Carbonyl Cluster as the Catalyst.