Inorganic Syntheses, Volume 35ISBN: 978-0-471-68255-4
Hardcover
224 pages
September 2010
 |
||||||
Contributors.
Dedication.
Notice to Contributors and Checkers.
Toxic Substances and Laboratory Hazards.
Chapter One COMPLEXES OF BULKY ß-DIKETIMINATE LIGANDS.
1. Introduction.
2. ß-Diketiminate Precursors HLMe,Me3 and TlLMe,Me3 (LMe,Me3 = 2,4-Bis-(Mesitylimido)Pentyl).
3. ß-Diketiminate Precursors LMe,iPr2H, [LMe,iPr2Li]x, and [LtBu,iPr2K]x (LMe,iPr2 = 2,4-Bis-(2,6-Diisopropylphenylimido)Pentyl; LtBu,iPr2 = 2,2,6,6-
Tetramethyl-3,5-Bis-(2,6-Diisopropylphenylimido)Heptyl).
4. ß-Diketiminate Precursors LtBu,iPr2H and LtBu,iPr2Li(THF) (LtBu,iPr2=2,2,6,6-Tetramethyl-3,5- Bis-(2,6-Diisopropylphenylimido)Heptyl).
5. Scandium Trichloride Tris(Tetrahydrofuran) and ß-Diketiminate-Supported Scandium Chloride Complexes.
6. ß-Diketiminate-Supported Titanium and Vanadium Dichloride Complexes.
7. ß-Diketiminate-Supported Vanadium and Chromium Chloride Complexes.
8. ß-Diketiminate-Supported Manganese and Zinc Complexes.
9. Iron 2,4-Bis-(2,6-Diisopropylphenylimido)Pentyl Chloride (LMe,iPr2FeCl).
10. Iron 2,2,6,6-Tetramethyl-3,5-Bis-(2,6-Diisopropylphenylimido)Heptyl Chloride (LtBu,iPr2FeCl).
11. Cobalt 2,2,6,6-Tetramethyl-3,5-Bis-(2,6-Diisopropylphenylimido) Heptyl Chloride (LtBu,iPr2CoCl).
12. ß-Diketiminate-Supported Nickel(II) and Nickel(I) Complexes of LMe,Me3 (LMe,Me3 = 2,4-Bis-(Mesitylimido)Pentyl).
13. Nickel 2,4-Bis-(2,6-Diisopropylphenylimido)Pentyl Chloride Dimer, [LMe,iPr2Ni(µ-Cl)]2.
14. Bis[Copper 2,4-Bis-(2,4,6-Trimethylphenylimido)Pentyl] Toluene, (LMe,Me3Cu)2(µ-n2:n2-C7H8).
15. Copper 2,4-Bis-(2,6-Diisopropylphenylimido)Pentyl Chloride (LMe,iPr2CuCl).
Chapter Two BORON CLUSTER COMPOUNDS.
16. Salts of Dodecamethylcarba-closo-Dodecaborate(—) Anion, CB11Me12, and the Radical Dodecamethylcarba-closo-Dodecaboranyl, CB11Me12.
17. Cesium Dodecahydroxy-closo-Dodecaborate, Cs2[B12(OH)12].
Chapter Three COORDINATION COMPOUNDS.
18. Pentaaquanitrosylchromium Sulfate.
19. The Tetradentate Bispidine Ligand Dimethyl-(3,7-Dimethyl-9-oxo-2,4-bis(2-pyridyl)-3,7-Diazabicyclo[3.3.1]nonane)-1, 5-dicarboxylate and Its Copper(ll) Complex.
20. Tris(2-Picolinyl)Methane and Its Copper(I) Complex.
Chapter Four CARBENE LIGANDS AND COMPLEXES.
21. 1,3-Dialkyl-Imidazole-2-Ylidenes.
22. A Chelating Rhodium N-Heterocyclic Carbene Complex by Transmetallation from a Silver–NHC Intermediate.
23. Rhodium and Iridium N-Heterocyclic Carbene Complexes from Imidazolium Carboxylates.
Chapter Five FUNCTIONAL LIGANDS AND COMPLEXES.
24. N-tert-Butyl ortho-Aminophenol, ortho-Iminoquinone, and a Zirconium(IV) bis(Aminophenolate) Complex.
25. Synthesis of the Water-Soluble Bidentate (P, N) Ligand PTN(Me) (PTN(Me) = 7-Phospha-3-methyl-1,3,5-triazabicyclo[3.3.1]nonane).
26. Synthesis of Metal-Organic Frameworks: MOF-5 and MOF-177.
Chapter Six ORGANOMETALLIC REAGENTS.
27. Tricarbonyl 1,3,5-Trimethyl-1,3,5-Triazacyclohexane Complexes of Chromium(0), Molybdenum(0), and Tungsten(0) [M(CO)3(Me3TACH) (M = Cr, Mo, W)].
28. Manganese Tricarbonyl Transfer (MTT) Agents.
29. Bis(1,5-Cyclooctadiene)Nickel(0).
30. Sodium (n5-Cyclopentadienyl)Tris(Dimethylphosphito-P) Cobaltate(III), Na[(C5H5)Co{P(O)(OMe)2}3].
Chapter Seven BIO-INSPIRED IRON AND NICKEL COMPLEXES.
31. Iron–Cyanocarbonyl Complexes [PPN][Fe(CO)4(CN)] and [PPN][FeBr(CO)3(CN)2].
32. Nickel Complexes of Bis(Diethylphosphinomethyl) Methylamine.
33. Monomeric Iron(II) Complexes Having Two Sterically Hindered Arylthiolates.
34 (1,3-Propanedithiolato)-Hexacarbonyldiiron and Cyanide Derivatives.
Chapter Eight RUTHENIUM COMPLEXES.
35. Ruthenium(II)-Chlorido Complexes of Dimethylsulfoxide.
36. Synthesis of Chloride-Free Ruthenium(II) Hexaaqua Tosylate, [Ru(H2O)6]tos2.
37. Basic Ruthenium Acetate and Mixed Valence Derivatives.
38. Di-µ-Chloro(Ethylbenzoate)Diruthenium(II), [(n6-etb)RuCl2]2.
Chapter Nine IRIDIUM COMPLEXES.
39. The Diphosphine tfepma and its Diiridium Complex Ir20,II(tfepma)3Cl2.
40. Heteroleptic Cyclometalated Iridium(III) Complexes.
41. Oxygen and Carbon Bound Acetylacetonato Iridium(III) Complexes.
Contributor Index.
Subject Index.
Formula Index.
Related Titles
General Inorganic Chemistry
Read Online Now at Wiley Online Library
An online version of this product is available through our
subscription-based content service.
Read Online
Read an Excerpt
.png){kind=small}
Join An E-mail ListLearn about the latest products, events, offers and content. |
