Inorganic Syntheses, Volume 33

1. Toward Magnetic Building Blocks: Synthesis of a Planar Co(III)–cation Radical–cobalt(III) Complex of the Binucleating Ligand 1,2,4,5-Tetrakis(2-hydroxy-2-methylpropanamido)benzene.

2. A Luminescent Decanuclear Ruthenium(II) Polypyridine Complex: A Convergent Approach to a Dendritic Structure Employing the "Complexes as Metals/Complexes as Ligands" Synthetic Strategy.

3. Dodecatungstoaluminic Acid and Its Monolacunary and Mixed-Addendum Derivatives.

4. Supramolecular Complexes of BisBis(2,2'-bipyridine)osmium(II) and Ruthenium(II).

5. Binuclear Oxomolybdenum–Metalloporphyrin Complexes.

6. Iron Sandwich Polyoxoanion Compounds.

7. Dipyrryl and Porphyrinic Precursors to Supramolecular Conjugated (Porphinato)metal Arrays: Syntheses of Dipyrrylmethane and (5,15-diphenylporphinato)zinc(II).

8. Synthesis of Dodecaoxohexadecacarboxylatotetraaquo-dodecamanganese [Mn₁₂O₁₂(O₂CR)₁₆(H₂O)₄] (R = Me,Et,Ph,Cr) Complexes.

9. Use of Picolinehydroximate Complexes in Preparation of Uranyl and Lanthanide 15-Metallacrown-5: UO₂(NO₃)₂ [15-MCCu(II)N(pic)-15] and {Eu(NO₃)₂[15-MCCu(II)N(pic)-15]}NO₃.

10. Use of Salicyl- and Naphthoylhydroximate Complexes in Preparation of Manganese and Copper 12-Metallacrown-4 Complexes: Mn(II)(Acetate)₂ [Mn(III)(salicylhydroximate)]₄ and (Tetramethylammonium)₂ [Cu(II)₅ (naphthoylhydroximate)₄].

Chapter Two USEFUL REAGENTS AND LIGANDS.

11. Homoleptic Transition Metal Acetonitrile Cations with Tetrafluoroborate or Trifluoromethanesulfonate Anions.

12. Synthesis of [M^II(NCMe)₆]²⁺ (M = V,Cr,Mn,Fe,Co,Ni) Salts of Tetra[3,5-bis(trifluoromethyl)phenyl]borate.

13. Transition Metal p-Toluenesulfonates.

14. Salts of Binuclear Iron(II) and Iron(III) Dianions [(Fe₂C_l6)^2- and (Fe₂OC_l6)^2-].

15. Tetraethylammonium-Tetrathioperrhenate Et₄N(ReS₄).

16. Large-Scale Synthesis of Methyltrioxorhenium (CH₃ReO₃).

17. 4,5-Diaminocatechol: A Useful Building Block in Synthesis of Multimetallic Complexes.

18. A Convenient Synthesis of 1,5,9-Trithiacyclododecane (S₃C₉H₁₈).

Chapter Three SOLID-STATE MATERIALS AND CLUSTERS.

19. Synthesis of Quaternary Selenophosphates using Molten Salt Fluxes: Rb₈Hg₄(Se₂)₂(PSe₄)₄, K₄In₂(PSe₅)₂(P₂Se₆), Rb₄Ti₂(P₂Se₇)(P₂Se₉)₂, Rb₄U₄(Se)₂(Se₂)₄(PSe₄)₄.

20. Hydrothermal Synthesis of Sulfosalts: Ag₃AsS₃, Ag₃SbS₃, Ag₇SbS₆, Cu₁₂Sb₄S₁₃, CuInS₂, FeIn₂S₄.

21. Open-Framework Solids of the Vanadium Oxide–Phosphate System.

22. Sulfur-Bridged Incomplete Cubane-Type Molybdenum and Tungsten Aqua Ions.

23. Sulfur-Bridged Cubane Type Mixed-Metal Clusters with Mo₃MS₄ (M = Fe,Co,Ni,Cu,In,Sn) and W₃NiS₄ Cores.

24. Molybdenum and Tungsten Clusters as Aqua Ions [M₃Q₄(H₂O)₉]⁴⁺ (M = Mo,W; Q = S,Se) and Related Chalcogen-Rich Trinuclear Clusters.

Chapter Four COMPOUNDS OF GENERAL INTEREST.

25. The Diphenylmethylenethiophosphinate (MTP) Ligand in Gold(I), Platinum(II), Lead(II), Thallium(I), and Mercury(II) Complexes, sym-Au₂(MTP)₂, (PPN)[Au(MTP)₂], Au₂Pt(MTP)₄, Au₂Pb(MTP)₄, AuTl(MTP)₄, Hg(MTP)₂, Hg(MTP)₂(AuCl)₂, and Hg^IIAu^I(MTP)₂Au^IIIC_l4.

26. Mesityl-gold(I) Complexes.

27. An Improved Synthesis of cis-Dithiocyanato-bis(4,4'-dicarboxy-2,2'-bpy) Ru(II) Sensitizer.

28. Dimethylsulfoxide Complexes of Platinum(II): K[PtCl₃(Me₂SO)], cis-[PtCl₂L(Me₂SO)] (L = Me₂SO,MeCN), [PtCl(μ-Cl)(Me₂SO)]₂, and [Pt(Me₂SO)₄](CF₃SO₃)₂.

29. Tetrasulfur-tetranitride (S₄N₄).

30. Hydrotris(methimazolyl)borate.

31. Arsenic(III)bromide.

32. Dichlorodioxo-bis(triphenylphosphine oxide)uranium(VI) [UO₂C_l2(OPPh₃)₂].

33. Chlorohydro-tris(pyrazol-1-yl)borato-bis(triphenylphosphine) ruthenium(II) {RuCl[k³-HB(pz)](PPh₃)₂} (pz = pyrazol-1-yl).

34. Octacarbonyl-di-μ-hydridodirhenium [Re₂(μ-H)₂(CO)₈].

35. Zero-Valent Binuclear Nickel Complexes.

36. Preparation of a Synthetic Ribonuclease: The Europium(III) Complex of 1-(4-nitrobenzyl)-4,7,10-Tris(carbamoylmethyl)-1,4,7,10- tetraazacyclododecane.

37. Carbonyl Halide Tungsten(II) Complexes of Tris(3,5-dimethylpyrazolyl)hydroborate.

38. A Luminescent Complex of Re(I): fac-[Re(CO)₃(bpy)(py)](CF₃SO₃) (bpy = 2.2'-bipyridine; py = pyridine).

39. RSi(OH)₃ and RSi(NH₂)₃ [R = 2,6-iPr₂C₆H₃N(SiMe₃)]: Synthesis of Stable Organosilanes with Three Functional Groups.

40. Fluorination with Me₃SnF: Synthesis of Cyclopentadienyl-Substituted Group 4 Metal Fluoride Complexes.

41. Seven-Coordinate [MI₂(CO)₃(NCMe)₂], [MI₂(CO)₃(NCMe)(PPh₃)], and Alkyne [MI₂(CO)(NCMe)(η²-RC₂R)₂] Complexes of Molybdenum(II) and Tungsten(II).

42. Chlorothiocarbonyl-bis(triphenylphosphine)iridium(I) [IrCl(CS)(PPh₃)₂].

Contributor Index.

Subject Index.

Formula Index.