Thermodynamics of Molecular SpeciesISBN: 978-0-471-01254-2
Hardcover
344 pages
December 1996
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Thermodynamic Components and Molecular Species.
Gibbs Free Energy, Chemical Equilibrium, and Correspondence Theorems.
Dilute Solutions, Standard Partial Free Energies, and the Stability Theorem.
Displacements from Equilibrium and Error Tolerance.
Linear Free-Energy Relationships, Transition-State Theory, and Error Tolerance.
Enthalpy-Entropy Compensation and Dormant Interactions.
Effect of Molar Shifts on State Functions.
Molar-Shift Terms in Dilute Solutions.
Hard-Sphere and Potential-Energy Cages Around Molecules in Liquids.
Environmental Isomers, Molecular Complexes and Cage Exchange in Liquids.
Solvation in Dilute Solutions.
Thermodynamics of Ionic Species.
References.
Index.
Gibbs Free Energy, Chemical Equilibrium, and Correspondence Theorems.
Dilute Solutions, Standard Partial Free Energies, and the Stability Theorem.
Displacements from Equilibrium and Error Tolerance.
Linear Free-Energy Relationships, Transition-State Theory, and Error Tolerance.
Enthalpy-Entropy Compensation and Dormant Interactions.
Effect of Molar Shifts on State Functions.
Molar-Shift Terms in Dilute Solutions.
Hard-Sphere and Potential-Energy Cages Around Molecules in Liquids.
Environmental Isomers, Molecular Complexes and Cage Exchange in Liquids.
Solvation in Dilute Solutions.
Thermodynamics of Ionic Species.
References.
Index.