Reagents for High-Throughput Solid-Phase and Solution-Phase Organic Synthesis

Introduction.

Recent Review Articles and Monographs.

4-Acetoxymethylbenzoic Acid.

N-[(Allyloxycarbonyl)oxy]maleimide-styrenne Copolymer (Alloc-resin).

Alumina.

5-[(4-Aminomethyl)-3,5-Dimethoxyphenoxy] Pentanoic Acod (PAL-Linker).

3-Amino-3-(2-nitrophenyl)propionoc Acid (ANP-linker).

0-(7-Azabenzotriazol-1-yl)-1,3-dimethyl-1,3-dimethylleneuronium hexafluorophosphate (HAMDU).

7-Azabenzotriazol-1-yloxytris(dimethyamino) phosphonium hexafluorosphate (AOP).

(7-Azabenzotriazol-1-yloxy)tris(pyrrolidino) phosphonium Hexafluorophosphate (pyAOP).

Azidation Polymer.

Azidotris(dimethylamino)phosphonium.

Hezafluorophosphate.

BEMP resin (PS-2-tert-butylimino-2-dimethylamino-1,3-dimethylperhydro-1,3,2-diazaphosphorine).

1,2-Benziodoxol-3(1H)-one,1-hydroxy,1-oxide (IBX).

1-Benzotriazolyl Diethyl Phosphate (BDP).

 (1H-Benzotriazol-1-yloxy)tripyrrolodino-phosphonium Hexafluorophosphate (pyBOP).

Benzotriazol-1-yloxytris(dimethylamino)phosphonium Hexafluorophosphate (BOP).

O-Benzotriazol-1-yl-N,N,N',N'-tetramethyluronium Hexafluorophosphate (HBTU).

O-Benzotriazol-1-yl-N,N,N',N'-tetramethyluronium Tetrafluoroborate.

Bis(2,4-dinitrophenyl) Carbonate.

Bis(o-nitrophenyl) Phenylphosphonate.

Bis(p-nitrophenyl) Ohenylphosphonate.

Bis(2-oxo-3-oxazolidinyl)phosphinic Chloride (BOP-CI).

Bis(pentafluorophenyl)carbonate.

1,1,3,3-Bis(tetramethylene)chlorouronium Hexafluorophosphate (pyCIU).

Bis(tricyclohexyphosphine)(4-polystyrylmethylidene) ruthenium Dichloride.

Borohydride Exchange Resin.

4-Bromomethyl-3-nitrobenzoic Acid.

4-(2-Bromopropionyl)phenoxyacetic Acid.

Bromotripyrrolodinophosphonium Hexafluorophosphate (pyBroP).

1,1'-Carbonylbis(3-methylimidazolium) Bis(trifluoromethanesulfonate).

N,N'-carbonydiimidazole (CDI).

Celite.

6-Chloro-1-(p-chlorobenzenesulfonyloxy) benzotriazole.

2-Chloro-1,3-demthylimidazolidium Hezafluorophosphate (CIP).

6-Chloro-2,4-dimethyoxy-s-triazine (CDMT).

Chlorotripyrrolidinophosphonium Hexafluorophosphate (pyCIOP).

copper(II) Nitrate - K10 Bentonite Clay.

Cyanuric Flouride.

1-Cyclohexyl-3-(2-morpholinoethyl)carbodiimide.

1-Cyclohexyl-3-(2-morpholinoethyl)carbodiimide methop-toluenesulfontae.

1,3-Dicyclohexylcarbodiimide (DCC).

N,N-Diethanolaminomethyl Polystyrene (PS-DEAM).

Diethyl phosphorocyanidate (DEPC).

3-(Diethoxyphosphoryloxy)-1,2,3-benzo-trazin-4(3H)-one (DEPBT).

1,3-Diisopropylcarbodiimide (DIC).

2,4-Dimethoxy-4'-hydroxybenzophenone.

4-[(2,4-Dimethoxyphenyl){[1-(9H-fluoren-9-ylmethoxy)carbonyl]amino}methyl]phenoxyacetric Acid (Rink Amide-linker).

N-[(Dimethylamino)-1H-1,2,3-triazolo[4,5-b]pyridin-1-ylmethylene]-N-methylmethanaminium.

Hexafluorophosphate N-Oxide (HATU).

Diphenyl phosphorochloridate.

2-Ethoxy-1-ethoxycarbonyl-1,2-dihydroquinoline (EEDQ).

1-Ethyl-3-(3'-dimethylaminopropyl)carbodiimide hydrochloride (EDCI).

N-Ethyl-5-phenylisoxazolium-3'-sulfonate (Woodward's Reagent K).

4-{4-[1-[(9H-Fluoren-9-ylmethoxycarbonyl)amino]ethyl]-2-methoxy-5-nitrophenoxy}butanoic Acid.

5-[4-(9-Fluorenylmethyloxycarbonyl)aminomethyl-3,5-dimethoxyphenoxy]pentanoic acid (FMOC-PAL-linker).

Fluorous Alkoxyethyl Ether (AE(F),                   [4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoro-1-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecfluoro-                                 decyl)undecyloxy]ethene).         

Fluorous DEAD.

Fluorous DMSO (1,1,1,2,2,3,3,4,4-nonafluoro-6-(methanesulfinyl)hexane).

Fluorous Tetrahydropyranyl Ether (THP(F),                                                    2-benzenesulfinyl-3-heptadecafluorooctyltetrahydropyran). 

Fluorous TIPS Triflate.

4-(4-Formyl-3-methoxyphenoxy)-butanoic Acid                                       (FMPB-linker).       

4-Hydroxymethylbenzoic acid (HMBA-linker).

4-(4-Hydroxymethyl-3-methoxyphenoxy)butyric Acid (HMPB-linker).

4-(hydroxymethyl)phenoxyacetic Acid.

N-(3-Hydroxy-9Hxanthenyl-O-(9H-fluoren-9-yl)methylcarbamic Acid.

Iron(III) Chloride-Silica Gel.

JandaJel.

Merrifield Resin (chloromethylcopoly(styrene-divinylbenzene)).

1-(Mesitylene-2-sulfonyl)-3-nitro-1,2,4-triazole (MSNT).

N-Methylmorpholine Polystyrene (PS-NMM).

Montmorillonite K10.

Nafion-H.

2-(5-Norbornene-2,3-Dicarboximido_1,1,3,3-tetramethyluronium Tetrafluoroborate (TNTU).

S-(1-Oxido-2-pirydinyl)-1,13,3-tetramethylthiouronium Hexafluorophosphate (HOTT).

Ozone-Silica Gel.

Palladium on Carbon.

Palladium(II) Hydroxide on Carbon.

PAMAM Dendrimer Resin (DendroGel).

pd Nanoparticles.

Pentafluorophenyl Diphenylphosphinate (FDPP).

1H,1H,2H,2H-perfluorodecanethiol (Fluorous Thiol).

phenylbis[4-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl) phenyl]-phosphine (Fluorous Triphenylphosphine.

Platinum on Alumina.

Platinium (IV) Oxide.

(polyallyl)scandium Triflylamide Ditriflate (PA-Sc-TAD).

3,3'-polyBINOL.

poly[4-(diacetoxyiodo)styrene](PS-DIB).

poly(ethylene glycol)-supported burgess reagent (PEG-Burgess Reagent).

poly(ethylene glycol)-supported 1,4-phthalazinediyl Diether Hydroquinidine ((DHQD)2 PHAL Ligand).

poly(ethylene glycol)-supported Dialkylborane.

poly(ethylene glycol)-supported N-phenyl Triflimide.

poly(ethylene glycol)-supported Thiarylphosphine.

poly(exo-N-Hydroxy-7-oxabicyclo[2.2.1]hept-5-ene-2,3-dicarboximide) (ROMPGEL-N-Hydroxysuccinimide).

Polyhexamethylenecarbodiimide.

Polymer-bound Diisopropyl Chlorosilane.

Polymer-bound Diphenyl Chlorosilane.

Polymer-bound N-Hydroxysuccinimide.

Polymer-supported O-Allyisourea.

Polymer-supported Ammonium Periodate.

Polymer-supported O-Benzylisourea.

Polymer-supported Bis(acyloxy)bromate(I).

Polymer-supported Bis(acyloxy)iodate (I).

Polymer-supported Bis(azido)iodate(I).

Polymer-supported Carbonate.

Polymer-supported Hydroxide.

Polymer-supported O-Methylisourea.

Polymer-supported Perruthenate.

Polymer-supported Sulfonic Acid (Dowex 50W).

Polymer-supported Sulfonic Acid (Dowex 50x8).

Polymer-supported Tetrathiafulvalene.

Polymer-supported Thiophenol.

Polymer-supported p-Toluenesulfonyl Chloride and related reagents.

Polymer-supported 1,5,7-Triazabicyclo[4.4.0]dec-5-ene PTBD).

Polymer-supported Trialkylsilyl Cyanide.

Polymer-supported Trisamine.

Polystyrene.

Polystyrene-bound 1-Hydroxybenzotriazole (PS-HOBT).

Polystyrene-bound Dimethylaminopyradine (PS-DMAP) carbodiimide Hydrochloride (PS-EDCI).

Polystyrene-supported Methyleneriphenylphosphorane.

Polystyrene-supported Tosyl Azide.

Polystyrene-supported Triphonylphosphine.

Polystyrylboronic Acid.

Poly(4-vinylpyridine).

Poly(4-vinylpyridinium Bromide Dichromate).

Poly(4-vinylpyridinium Bromide Perbromide).

Potassium Flouride-Alumina.

Potassium Flouride-Celite.

Potassium Hydroxide-Alumina.

Potassium on Alumina.

N-[(Propargyloxycarbonyl)oxy]maleimidestyrene Copolymer (Proc-resin).

Pyridinium Chlorochromate-Alumina.

2-Pyridyldimethylsilane.

Rodium on Alumina.

Silver(I) Carbon on Celite.

Solid-supported Phosphine-free Ruthenium Alkylidene for Olefin Metathesis.

O-(N-Succinimidyl)-1,1,3,3-Tetramethyluronium Tetrafluoroborate (TSTU).

TEMPO-methyl-polystyrene resin Tentagel.

1,1,3,3-Tetramethylfluoroformamidinum Hexafluorophosphate (TFFH).

Tetramethylurea.

Triazene resin.

Triphenylmethyl Chloride resins.

Triphenylphosphine Selenide.

Tris(2-perfluorohexylethyl)tin Hydride (Fluorous Tin Hydride).

Wang Resin.

List of Contributers.

Reagent Fomula Index.

Subject Index.