Physical Inorganic Chemistry SetISBN: 978-0-470-58022-6
Hardcover
1000 pages
April 2010
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Physical Inorganic Chemistry: Reactions, Processes, and Applications
Preface ix
Contributors xi
1 Electron Transfer Reactions 1
Ophir Snir and Ira A. Weinstock
2 Proton-Coupled Electron Transfer in Hydrogen and Hydride Transfer Reactions 39
Shunichi Fukuzumi
3 Oxygen Atom Transfer 75
Mahdi M. Abu-Omar
4 Mechanisms of Oxygen Binding and Activation at Transition Metal Centers 109
Elena V. Rybak-Akimova
5 Activation of Molecular Hydrogen 189
Gregory J. Kubas and Dennis Michael Heinekey
6 Activation of Carbon Dioxide 247
Ferenc Joo
7 Chemistry of Bound Nitrogen Monoxide and Related Redox Species 281
Jose A. Olabe
8 Ligand Substitution Dynamics in Metal Complexes 339
Thomas W. Swaddle
9 Reactivity of Inorganic Radicals in Aqueous Solution 395
David M. Stanbury
10 Organometallic Radicals: Thermodynamics, Kinetics, and Reaction Mechanisms 429
Tamas Kegl, George C. Fortman, Manuel Temprado, and Carl D. Hoff
11 Metal-Mediated Carbon--Hydrogen Bond Activation 495
Thomas Brent Gunnoe
12 Solar Photochemistry with Transition Metal Compounds Anchored to Semiconductor Surfaces 551
Gerald J. Meyer
Index 589
Physical Inorganic Chemistry: Principles, Methods, and Models
Preface ix
Contributors xi
1 Inorganic and Bioinorganic Spectroscopy 1
Edward I. Solomon and Caleb B. Bell III
2 57Fe Mossbauer Spectroscopy in Chemistry and Biology 39
Marlene Martinho and Eckard Munck
3 Magnetochemical Methods and Models in Inorganic Chemistry 69
Paul Kogerler
4 Cryoradiolysis as a Method for Mechanistic Studies in Inorganic Biochemistry 109
Ilia G. Denisov
5 Absolute Chiral Structures of Inorganic Compounds 143
James P. Riehl and Sumio Kaizaki
6 Flash Photolysis and Chemistry of Transients and Excited States 199
Guillermo Ferraudi
7 Application of High Pressure in the Elucidation of Inorganic and Bioinorganic Reaction Mechanisms 269
Colin D. Hubbard and Rudi van Eldik
8 Chemical Kinetics as a Mechanistic Tool 367
Andreja Bakac
9 Heavy AtomIsotope Effects as Probes of Small Molecule Activation 425
Justine P. Roth
10 Computational Studies of Reactivity inTransition Metal Chemistry 459
Jeremy N. Harvey
Index 501